NOAA RESEARCH CRUISE -- RB-99-01

Atmospheric Aerosols and Climate Change

NOAA Ship Ronald H. Brown

January 14 – February 20, 1999





Summary of Cruise Description and Objectives:

The NOAA/OGP Aerosols Project seeks to provide improved information about the radiative forcing of human-influenced particles on the climate system in order to (i) aid the detection and attribution of climate change, in particular, the estimation of the offset that anthropogenic aerosols may be providing to the greenhouse-gas induced warming and the regional forcing induced by inhomogeneous aerosol distributions and (ii) improve the prediction of future climate changes for various radiative-forcing scenarios. This cruise is designed to measure the chemical, physical, optical and cloud-nucleating properties of aerosols in the marine boundary layer of the Atlantic and Indian Oceans. Aerosol data in these regions are extremely sparse which currently limits our ability to constrain chemical transport and radiative transfer models. The data obtained on this cruise will provide regional means and variability of aerosol precursor gases and aerosol properties as a function of airmass origin. The data will ultimately yield more realistic estimates of the forcing of climate by aerosols relative to recent estimates (e.g., IPCC(1995)) which rely for the most part on estimated global mean aerosol optical properties.

Measurements will be conducted continuously while the ship is in transit from the US to the Indian Ocean. The ship will stop daily during the SeaWiFS overpass (approximately noon) and every third day during the AVHRR overpass (mid-afternoon) to sample the upper water column. Many of the same measurements will continue in the Indian Ocean as part of INDOEX. Measurements include:

--surface seawater measurements of dimethylsulfide, ammonia, nitrate, carbon dioxide, chlorophyll fluorescence, salinity, and temperature,

--atmospheric measurements of dimethylsulfide, sulfur dioxide, carbon monoxide, carbon dioxide, ammonia, radon, nitrogen oxides, in-situ and column ozone, aerosol physical, optical and hygroscopic properties, total condensation nuclei population, cloud condensation nuclei population, aerosol optical depth, size resolved aerosol chemical composition including major anions and cations, mineral dust, and organic and elemental carbon, and aerosol backscatter, major cations and anions in precipitation,

--routine weather observations (air temperature, dew point temperature, wind speed and direction, barometric pressure and light levels at several spectra), and rawindsonde balloon launches for atmospheric temperature, dew point and winds,

--water leaving radiance, solar irradiance, diffuse sky radiance

--satellite observations of aerosol optical depth, aerosol number/size, ocean color.

--CTD/optical casts for up and downwelling radiance, PAR, fluoresence, transmisivity.

--CTD/rosette casts for chlorophyll, pigments, total absorption of suspended material, nitrogen isotopes.
 
 

1.0 SCIENTIFIC OBJECTIVES

Aerosols and Climate -- Atmospheric aerosol particles affect the Earth's radiative balance both directly through the upward scatter of solar radiation and indirectly as cloud condensation nuclei (CCN). The natural aerosol derived from biogenic sulfur emissions has been substantially perturbed by anthropogenic aerosols, particularly sulfates from SO2 emissions and organic condensates and soot from biomass and fossil fuel combustion. The global mean radiative forcing due to the direct effect of anthropogenic sulfate aerosol particles is calculated to be of comparable magnitude but opposite in sign to the forcing due to anthropogenic CO2 and the other greenhouse gases. More uncertain is the radiative forcing due to the indirect cloud-mediated effects of aerosol particles. Although aerosol particles have a potential climatic importance over and down wind of industrial regions that is equal to that of anthropogenic greenhouse gases, they are still poorly characterized in global climate models. This is a result of a lack of both globally distributed data and a clear understanding of the processes linking gaseous precursor emissions, atmospheric aerosol properties, and the spectra of aerosol optical depth and cloud reflectivity. At this time, tropospheric aerosols pose one of the largest uncertainties in model calculations of the climate forcing due to anthropogenic changes in the composition of the atmosphere. Clearly, considerable attention must be focused on quantifying the processes controlling the natural and anthropogenic aerosol and on defining and minimizing the uncertainties in the calculated climate forcings.

The primary goal of this cruise is to make in-situ measurements of the chemical, physical, optical and cloud-nucleating properties of aerosols in the marine boundary layer of the Atlantic and Indian Oceans. Total column aerosol properties will be assessed remotely using shipboard sunphotometers and LIDAR and satellite observations (SeaWiFS and AVHRR). Aerosol data in these regions of the ocean are extremely sparse which currently limits our ability to constrain chemical transport and radiative transfer models. The data obtained on this cruise will provide regional means and variability of aerosol precursor gases and aerosol properties as a function of airmass origin. The data will ultimately yield more realistic estimates of the forcing of climate by aerosols relative to recent estimates (e.g., IPCC(1995)) which rely for the most part on estimated global mean aerosol optical properties.

Trace Gases and Climate -- Trace gases in the marine boundary layer affect the Earth’s radiative and chemical balance by absorbing the long-wave radiation leaving the Earth (green-house gases) and by altering the oxidative capacity of the atmosphere. The concentrations of these chemically reactive and infrared-active trace gases are increasing in the atmosphere due to anthropogenic activities. There is considerable scientific evidence that the increasing atmospheric concentrations of these gases will lead to a global warming which could have disruptive consequences world-wide. Predicting future concentrations of these gases and their potential climatic effects requires an improved understanding of their atmospheric sources and sinks and the processes controlling their concentrations. The goals of the trace gas programs participating in this cruise are:

  1. to assess the oceanic sources and sinks of the radiatively and reactively important trace species,
  2. assess the oceanic and atmospheric distributions and properties of the key species, and
  3. to understand the processes controlling the oceanic and atmospheric concentrations and assess the sensitivity of these systems to anthropogenic and natural perturbations.
Satellite Validation and Global Analysis -- As satellite operations for oceanic and atmospheric parameters become more abundant, there is a growing need to validate space-borne measurements. Seawater optical measurements and chlorophyll and pigment data are needed to validate SeaWiFS ocean color retrievals. Water-leaving radiance, sunphotometer and aerosol lidar measurements are essential for validating aerosol measurements from SeaWiFS, AVHRR, and TOMS. Although sunphotometers in the aerosol network known as AERONET (http://spamer.gsfc.nasa.gov) are stationed at a number of Atlantic, South American and African sites, this cruise will supply validating measurements in open ocean away distant from coastal and island effects. Radiosonde data in the central Atlantic and, especially near the African coast, will be ingested into global models (eg by NCEP) for better weather forecasting and post-cruise model analysis.

Ozonesondes profiles will comprise unique data; such launches have been performed previously on Europe-to-South America cruises but not from North America to southern Africa and thence to the Indian Ocean. The mid-latitude-sub-tropical-tropical transition in ozone profiles is of interest to researchers using global and regional models to study ozone transport and for development of aerosol and tropospheric ozone satellite products from TOMS (see http://jwocky.gsfc.nasa.gov for aerosol products). New tropical tropospheric ozone maps (TTO; http://metosrv2.umd.edu/~tropo) will be validated with the daily ozone profile data to be collected on the cruise. The MicroTOPS record of total column ozone and the ozonesonde data set will be part of the SHADOZ (Southern Hemisphere ADditional OZonesondes) TOMS validation project. SHADOZ ground sites at Natal (Brazil, 6° S, 35° W), Ascension Island (8S, 15° W), and Reunion Island (21° S, 55° E) are very close to the cruise track.

Additional SHADOZ data to be taken during the cruise will be at Kashidoo Observatory in the Maldives, at Watukosek (Indonesia, 7° S, 112° E), and at Fiji, Tahiti, American Samoa, Galapagos and Easter Island. The latter five sites are part of the NASA PEM-Tropics B DC-8 campaign which will coincide with the either the latter part of this cruise and the INDOEX cruise. The Japanese SOWER project is supplying ozone launches at Galapagos and hopes to launch in the January-March time frame on Christmas Island as well. These ozone profiles, with the complete SHADOZ data set, and the unique contribution of the ozonesondes launched on this cruise, will make the January-February 1999 period unprecedented in longitudinal and latitudinal ozonesonde coverage in the southern hemisphere tropics and sub-tropics.

2.0 PERSONNEL

2.1 Participating Organizations:
 
NOAA Pacific Marine Environmental Lab., Seattle, WA (PMEL)
University of Washington, Seattle, WA (UW)
Naval Postgraduate School, Monterey, CA (NPGS)
Joint Institute Study Atmosphere Ocean, Seattle, WA (JISAO)
Inst. for Tropospheric Research, Leipzig, Germany (IfT)
Stockholm University, Stockholm, Sweden (MISU)
University of Maryland, College Park, MD (UMD)
Princeton University, Princeton, NJ (PU)
NASA/Goddard Space Flight Center, Greenbelt, MD (NASA)
Scripps Institution of Oceanography, La Jolla, CA (SIO)
NOAA Climate Mon. & Diag. Lab., Boulder, CO (CMDL)
NOAA Atlantic Ocean. & Met. Lab., Miami, FL (AOML)
Max Planck Institute for Chemistry, Mainz, Germany (MPI)
NOAA Air Resources Laboratory, Silver Springs, MD (ARL)
University of Miami, Miami, FL (UM)
University of Bremen, Germany (IUP)
Brookhaven National Laboratory (BNL)

 
 
 

2.2 Participating Scientists
 
Name Gender Nationality Affiliation Leg 1 Leg 2
Dr. Timothy Bates M USA PMEL X X
Dr. James Johnson M USA JISAO/PMEL X X
Mr. Derek Coffman M USA JISAO/PMEL X X
Dr. Theresa Miller F USA JISAO/PMEL X X
Mr. Drew Hamilton M USA JISAO/PMEL X X
Dr. Zhen Yang M China NRC/PMEL X X
Dr. Anne Thompson F USA NASA X  
Dr. Martina Schmeling F Germany PU X  
Mr. Andreas Massling M Germany IfT X X
Mr. Andreas Nowak M Germany IfT X
Mr. Stephan Leinert M Germany IfT X X
Mr. Michael Norman M Sweden MISU X X
Dr. Anders Karlsson M Sweden MISU X X
Dr. Bruce Doddridge M Australia UMD X X
Dr. Russell Dickerson M USA UMD   X
Dr. Winston Luke M USA ARL X  
Ms. Wilnetta Ball F USA UMD   X
Mr. Charles Piety M USA UMD X X
Dr. Robert Frouin M USA SIO X X
Mr. Alexandre Paci M France SIO X X
Dr. Greg Mitchell M USA SIO   X
Dr. Tom Carsey M USA AOML   X
Mr. Mike Shoemaker M USA AOML X  
Mr. Mike Farmer M USA AOML   X
Dr. Volker Wagner M Germany MPI   X
Dr. Corinne Schiller F Canada MPI   X
Dr. Uwe Parchatka M Germany MPI   X
Dr. Andreas Zahn M Germany MPI   X
Dr. Mike Reynolds M USA BLN X  
Dr. Ken Voss M USA UM X  
Dr. Ellsworth Welton M USA UM   X
Mr. Bob Castle M USA AOML X X
Dr. Lola Hernandez F Spanish IUP X X
Mr. Lars Reichert M German IUP   X
Mr. Jorn Burkert M German IUP   X
total scientists       23 29

 

3.0 SCHEDULE
 
Depart  Arrive
Leg 1 (26 days) Norfolk, Virginia

14 January 1999

Cape Town, South Africa

8 February 1999

Leg 2 (10 days) Cape Town, South Africa

11 February 1999

Port Louis, Mauritius

20 February 1999

total sea/ship days 36 (+ 2 days in South Africa)
 
 

4.0 OPERATIONS

4.1 Underway Measurements

The following continuous measurements will be made aboard RONALD H. BROWN during transit and while on station:

Atmospheric Chemical Measurements

Mass size distributions of nss sulfate, MSA, ammonium, and other major ions with a seven stage multi-jet cascade impactor at 55% RH. Sampling time periods will range from 12 to 24 hours. (Quinn, PMEL)

Mass size distributions of metals by trace metal TXRF with a seven stage multi-jet cascade impactor at 55% RH. Sampling time periods will range from 12 to 24 hours. (Russell, PU)

Sub- and super-micron nss sulfate, MSA, ammonium, and other major ions with a two stage multi-jet cascade impactor. Upper size cuts will be 1.0 and 10.0 m m diameter at 55% RH. Sampling time periods will be 4 to 6 hours. (Quinn, PMEL)

Sub- and super-micron nss sulfate, MSA, ammonium, and other major ions with a two stage filter pack mounted outside at ambient RH. Sampling time periods will be approximately 24 hours. (Leck, MISU)

Sub- and super-micron elemental and organic carbon by combustion and Raman spectroscopy. Upper size cuts will be 1.0 and 10.0 m m diameter at 55% RH. Sampling time periods will be 12 to 24 hours. (Wiedenshohler, IfT)

Sub- and super-micron mineral dust using XRF and SEM/XRF. (Quinn, PMEL)

Gas phase measurements of SO2 and NH3 (Leck, MISU), DMS (Bates, PMEL), O3 (surface and vertical profiles with MicroTops and ozonesondes)(Johnson, JISAO & Thompson, NASA), PAN and nitrogen oxides (Carsey & Farmer, AOML), 222Rn (Johnson & Hamilton, JISAO & Whittleson, ANSTO), CO2 (Feely, PMEL and Wanninkhof, AOML), CO, SO2, jNO2 (Dickerson, UMD), H2CO, H2O2, NO2, and CO by TDLA (Fischer, MPI, Leg 2 only), j(O3) using filter radiometers (Fischer, MPI, Leg 2 only), Rox (Burrows, Bremen).
 
 

Aerosol Physical and Optical Measurements Gravimetric analysis of mass as a function of size with a seven stage multi-jet cascade impactor at 55% RH. (Quinn, PMEL)

Total number concentration of CN with Dp>15 nm and CN with Dp>5 nm using TSI 3010 and 3025 particle counters, respectively. (Bates, PMEL & Covert, UW)

Particle number size distribution from 5 to 5000 nm diameter using an UDMPS, DMPS, and TSI 3300 APS. (2 systems, dry and 55% RH) (Bates, PMEL; Covert, UW; Wiedensohler, IfT)

Particle number size distribution from 200 to 20000 nm using a CSASP-200 PMS probe (Durkee, NPGS)

Hygroscopic growth of aerosol particles with TDMA. (Wiedensohler, IfT)

Total aerosol light scattering and the backscattered fraction at wavelengths of 450, 550, and 700 nm.(Quinn, PMEL)

Total aerosol light absorption at 500 nm using a PSAP. (Quinn, PMEL)

Aerosol optical depth with hand-held sunphotometers. (Quinn, PMEL)

AVHRR and SeaWiFS satellite observations of aerosol optical depth, aerosol number/size (Johnson, PMEL; Durkee, NPGS).

Aerosol backscatter using Micro-Pulse LIDAR (Voss, UM)
 
 

Seawater Measurements DMS (Bates, PMEL)

Ammonia (Quinn, PMEL)

pCO2, chlorophyll, oxygen (Feely, PMEL & Wanninkhof, AOML)

Fluoresence, transmisivity, chlorophyll, HPLC pigments, total absorption of suspended matter in the upper water column (Frouin, SIO)

Nitrogen isotopic composition of DON and nitrate (Sigman, PU)
 
 

Radiation Measurements Waterleaving radiance using a SIMBAD system (Frouin, SIO)

Solar irradiance and diffuse sky radiance spectra at several wavelengths using a PREDE system (Frouin, SIO)

Solar irradiance and diffuse sky radiance spectra at several wavelengths using a sky rads system and the aureole system (Voss, UM)

Up and downwelling radiance and PAR in the upper water column (Frouin, SIO)

Shortwave global irradiance in six 10 nm bands, one broadband, and from an Eppley PSP using a Portable Radiation Package (PRP) with a Fast Rotating Shadowband Radiometer (FRSR) (Reynolds, BNL)
 
 

Ancillary Measurements Surface air temperature, dew point, wind speed, wind direction, precipitation amount and frequency, solar insolation (Johnson & Hamilton, JISAO).

Vertical profiles of atmospheric temperature, dew point and winds (Johnson, JISAO).

Surface seawater temperature, salinity, chlorophyll a, and nitrate (Johnson & Hamilton, JISAO).
 
 

Air samples will be collected using equipment mounted on the forward part of the 02 level. A mast will extend approximately 8 meters above the deck for air sampling lines. Additional air sampling lines will run from this location to the oceanographic laboratories and laboratory van (Al Van) on 01 level port side.

Atmospheric samples will also be collected from the AOML bow tower. The tower will be installed on the ship before departure from the U.S.

Ship and scientific personnel must constantly be aware of potential sample contamination. Work activities forward of the main stack must be secured during sampling operations. This includes the bow, boat deck forward of the stack, bridge deck and flying bridge. The scientists on watch must be notified of any change in ship course or speed that will move the relative wind abaft the ship's beam or if anyone needs access to the bow. The scientists on watch should also be notified when the ship enters a rain squall and when the rain subsides.

Continuous water sampling will be made from the ship's bow intake system. This system must be capable of delivering 75 liters per minute through the main deck piping. Seawater will be drawn off this line to the Al Van on 01 level port side and the sea/air CO2 equilibrator in the hydro lab. Care must be taken to prevent contamination from smoke, solvent, cleaning solutions, etc.

4.2 Station Operations

A CTD/optics (SIO CTD deployed from stern A-frame) and a CTD/rosette (ship’s system deployed from starboard side) cast will be made each day at the time of the SeaWiFS satellite overpass. On clear days an in-water radiance distribution camera system will be deployed from the stern. This package is placed in the water and floated away, while tethered, from the ship. Atmospheric and surface seawater sampling will continue while on station. The ship will remain headed into the wind to prevent contamination from the ship's exhaust and vents. Again, extreme care must be exercised to prevent contamination of the air samples. The scientists on watch must be notified of any ship operation that will move the relative wind abaft the ship's beam.

CTD operations will be conducted by the survey department and scientists from SIO. Maximum cast depth for the CTD/rosette cast will be 300m with most samples collected in the photic zone (6-8 depths). Water from the rosette cast will be sampled for chlorophyll, HPLC pigments, and absorption by total suspended matter.

An additional station will occur every third day during the AVHRR overpass (mid-afternoon). A CTD/optics and CTD/rosette cast will be performed if the sky is clear.

4.3 Balloon Launches

Atmospheric temperature, humidity and wind profiles will be obtained from rawindsondes released from the ASAP van twice per day at 1100 and 2300 UCT. The data from these launches will be sent by the ship to the national weather service. An ozonesonde will be launched from the ship’s fantail once per day by NASA personnel.
 
 

5.0 FACILITIES

5.1 Equipment and capabilities to be provided by ship

The following systems and their associated support services are essential to the cruise. Sufficient consumables, back-up units, and on-site spare parts and technical support must be in place to assure that operational interruptions are minimal. All measurement instruments are expected to have current calibrations and all pertinent calibration information shall be included in the data package.

(a) Navigational systems including high resolution GPS.

(b) CTD/rosette sampling systems. The CTD system will be operated by ship's personnel. Specific requirements for this system are: -- 2 CTD capable winch systems with 500 meter depth capability, -- CTD stand and rosette, -- Niskin bottles with silicon O-rings and tubing (12 ea, 10 liter). (c) Autosal Salinometer and salinity sample bottles.

(d) Thermosalinograph calibrated to within 0.1°C and 0.01 ppt.

(e) Dry compressed air (120 psi, 4 CFM) to the pump van. Power, water and telephone connections to vans (see section 5.2).

(f) Continuously flowing seawater to the vans and equilibrator (minimum of 75 liters per minute).

(g) Laboratory/work space.

(h) Freezer space for air and seawater samples.

(i) Refrigerator space (10 cubic feet) for air samples (no chemicals).
 
 

5.2 Equipment, capabilities and supplies provided by scientific party
 
 

(a) Vans (van locations are shown in appendix C)
 
1) Chemistry van (AL van)
wt 10,000 lbs  
size 8' X 20'  
power 30 amps 480 v three phase  
location port side 01 level  
Needs freshwater and clean seawater lines and phone.

Load in Seattle Offload at end of field season

 
2) Aerosol van
wt 12,000 lbs  
size 8' X 18'  
power 50 amp 448 v three phase  
location port side 02 level  
Needs a phone and freshwater. 

Load in Seattle, Offload at end of field season

 
3) Pump van
wt 5,000 lbs  
size 7' X 12'  
power From aerosol van  
location aft of Aerosol van, 02 level  
Needs compressed air (120 psi/4 CFM).

Load in Seattle, Offload at end of field season

 
4) Spare parts/storage van,
wt 12,000 lbs  
size 8' X 20'  
power none  
location port side, 01 level  
Load in Seattle, Offload at end of field season
 
5) Ammonia-Sulfur Dioxide van,
wt 4,000 lbs  
size 8' x 10'  
power 480 v, 30 amps single phase  
location port side, 02 level  
Needs phone, fresh water

Load in Seattle, Offload at end of field season

 
6) AOML van
Wt 5,000 lbs  
Size 12' x 8’  
Power 480 v, 30 amps single phase   
Location 02 level  
Load in Norfolk, Offload at end of field season or in Darwin if space is not available

Needs freshwater line and phone.

 
7) MPI Van
Wt 18,000 lbs  
Size 8’ x 20'  
Power from MPI power/nitrogen van  
needs phone, compressed air and fresh water

Load in Cape Town, Offload at end of INDOEX

 
8) MPI power/nitrogen Van
wt 18,000 lbs  
size 8’ x 20'  
power 480 v, 30KVA  
location 02 level  
needs compressed air

Load in Cape Town, Offload at end of field season

 
9) SIO Van
wt 4,000 lbs  
size 7.5’ x 13.5'  
power 480 v, 30 amp, single phase  
location Main deck  
needs phone and fresh water

Load in Norfolk, Offload at end of INDOEX

(b) Air sampling equipment including pumps, flowmeters, filters, ozone and soot analyzer, aerosol sizing instrumentation, condensation nuclei counter, and cloud condensation nuclei counter

(c) Chemical analysis instrumentation including gas chromatographs, equilibrators, ion chromatographs, glove boxes, autoanalyzers, fluorometers, and pH meter.

(d) Chemical reagents, compressed gases (approximately 140 cylinders), and liquid nitrogen (1000 liters). A complete listing of all chemicals to be brought onboard is included in Appendix B. Material Data Safety Sheets will be provided to ship before any chemicals are loaded.

(e) CTD/Optics system and winch (480 V, 20 amps, 4’x4’ footprint, 3500 lbs)

(f) Bow tower to be mounted in Norfolk.

Samplers on tower:

Portable Radiation Package (PRP)

CSASP (NPGS) for aerosol number size distribution

Rainwater collectors (MISU)

IMPROVE aerosol sampler

(g) Micropulse LIDAR to be mounted on 03 level forward.

(h) Chest freezer for storing organic samples. (i) Aerosol sampling mast on the aerosol container van. Inlets will be used for:
    1. Nephelometer/PSAP (PMEL)
    2. DMPS Number sizing system (UW/PMEL)
    3. APS (PMEL) and APS (IfT)
    4. DMPS/ Tandem DMAs (IFT)
    5. Sodium number size distribution (PU) and CN counters (PMEL)
    6. 7-stage impactor for trace metals (PU)
    7. 2-stage impactor for organic and elemental carbon (IFT)
    8. 2-stage impactor for organic carbon speciation (IfT)
    9. 2-stage impactor for organic and elemental carbon (PMEL)
    10. 2-stage impactor for gravimetric analysis (PMEL)
    11. 7-stage impactor for gravimetric analysis (PMEL)
    12. 2-stage impactor for ions (PMEL)
    13. 7-stage impactor for ions (PMEL)
    14. 2- stage impactor for mineral dust (PMEL)
    15. 2-stage impactor for SEM XRF (PMEL)
  1. Rawindesondes, ozonesondes, balloons and helium (60 tanks)
  2. PREDE radiometer to be mounted on 03 level forward.
  1. Gimbal mounted whole sky camera (RADS) system to be mounted on 03 level forward.
  1. Motor generator to produce 50 Hz power for MPI
  2. Liquid nitrogen generator (MPI)
  3. Spare CTD/rosette/niskin bottles (SIO)
6.0 DISPOSITION OF DATA AND REPORTS

6.1 Data responsibilities

The Chief Scientist is responsible for the disposition, feedback on data quality, and archiving of data and specimens collected on board the ship for the primary project. The Chief Scientist is also responsible for the dissemination of copies of these data to participants on the cruise and to any other requesters. The ship will assist in copying data and reports insofar as facilities allow. The ship will provide the Chief Scientist copies of the following data:

Sightings log (position, speed, course, distance upwind) of other vessels

Autosal salinity analysis logs

Navigational log sheets (MOAs)

Weather observation sheets

Autosal calibration reports

Thermosalinograph calibration reports

CTD cast logs

CTD calibration reports

CTD data in ASCII format

Weather maps

SCS data tapes

The Chief Scientist will receive all original data gathered by the ship for the primary and piggy-back projects, and this data transfer will be documented on NOAA form 61-29 "Letter Transmitting Data". The Chief Scientist in turn will furnish the ship a complete inventory listing of all data gathered by the scientific party, detailing types and quantities of data.

The Commanding Officer is responsible for all data collected for ancillary projects until those data have been transferred to the projects' principal investigators or their designees. Data transfers will be documented on NOAA Form 61-29. Copies of ancillary project data will be provided to the Chief Scientist when requested. Reporting and sending copies of ancillary data to NESDIS (ROSCOP) is the responsibility of the program office sponsoring those projects.

6.2 Ship operation evaluation report

A Ship Operations Evaluation Report will be completed by the Chief Scientist and given to the Director, PMEL, for review and then forwarded to NC3.

6.3 Foreign research clearance reports

A request for research clearance in foreign waters (United Kingdom for Ascension Island and St. Helena, Nambia, S. Africa, Swaziland, Mozambique, Madagascar, France for Reunion Island and Mauritius) has been submitted by PMEL. Copies of clearances received will be provided to the FOO before departure. The Chief Scientist is responsible for satisfying the post-cruise obligations associated with diplomatic clearances to conduct research operations in foreign waters. These obligations consist of (1) submitting a "Preliminary Cruise Report" immediately following the completion of the cruise involving the research in foreign waters (due at ONCO within 30 days); and (2) ultimately meeting the commitments to submit data copies of the primary project to the host foreign countries.
 
 

7.0 ADDITIONAL INVESTIGATIONS AND PROJECTS

Any additional work will be subordinate to the primary project and will be accomplished only with the concurrence of the Chief Scientist and Commanding Officer on a not-to-interfere basis.

The following ancillary projects will be conducted by ship's personnel in accordance with general instructions contained in the PMC OPORDER:
 
(a) SEAS Data Collection and Transmission  (PMC OPORDER 1.2.1)
(b) Marine Mammal Reporting  (PMC OPORDER 1.2.2)
(c) Sea Turtle Observations  (SP-PMC-2-89)
(d) Bathymetric Trackline  (PMC OPORDER 1.2.5)

7.1 No ancillary projects are assigned.

8.0 COMMUNICATIONS

The ship is equipped with INMARSAT, a telephone / teletype satellite communication system. If the scientific staff uses this system, they will be obligated to pay for their calls, which are estimated at $6.02 per minute for voice or rapid fax and $4.00 per minute for Telex. The Chief Scientist or designee will have access to and assistance provided for transmitting and receiving communications through INMARSAT as needed during the cruise. The ship’s INMARSAT number is 011-sat-154-2643 (voice) 011-sat-154-2644 (fax) where sat is the satellite = 872 (Pacific West), 871 (Atlantic East), or 873 (Indian).

The ship has recently been equipped with INMARSAT M capabilities. The cost is estimated at $2.99 per minute. The INMARSAT M telephone number is 011-sat-761-266-581.

An account for ccmail for embarked personnel will be established by the RONALD H. BROWN Electronics Technician; the general format is first_last%brown@ccmail.rdc.noaa.gov. Ccmail will be sent and received two times per day.

9.0 HAZARDOUS MATERIAL

The RONALD H BROWN will operate in full compliance with all environmental compliance requirements imposed by NOAA. All hazardous materials/substances needed to carry out the objectives of the embarked science mission, including ancillary tasks, are the direct responsibility of the embarked designated Chief Scientist, whether or not that Chief Scientist is using them directly. The RONALD H BROWN Environmental Compliance Officer will work with the Chief Scientist to ensure that this management policy is properly executed, and that any problems are brought promptly to the attention of the Commanding Officer.

All hazardous materials require a Material Safety Data Sheet (MSDS). Copies of all MSDSs shall be forwarded to the ship at least two weeks prior to sailing. The Chief Scientist shall have copies of each MSDS available when the hazardous materials are loaded aboard. Hazardous material for which the MSDS is not provided will not be loaded aboard.

The Chief Scientist will complete a local inventory form, provided by the Commanding Officer, indicating the amount of each material brought onboard, and for which the Chief Scientist is responsible. This inventory shall be updated at departure, accounting for the amount of material being removed, as well as the amount consumed in science operations and the amount being removed in the form of waste. A list of chemicals and gases that will be brought onboard the ship for this cruise is listed in B. PMEL gases and chemicals will be loaded in Seattle; CO2-AOML, AOML, UMD, MISU, PU gases and chemicals will be loaded in Norfolk; MPI gases and chemicals will be loaded in Cape Town.

The ship’s dedicated HAZMAT Locker contains two 45-gallon capacity flam cabinets and one 22-gallon capacity flam material cabinet, plus some available storage on the deck. Unless there are dedicated storage lockers (meeting OSHA/NFPA standards) in each van, all HAZMAT, except small amounts for ready use, must be stored in the HAZMAT Locker.

The scientific party, under the supervision of the Chief Scientist, shall be prepared to respond fully to emergencies involving spills of any mission HAZMAT. This includes providing properly-trained personnel for response, as well as the necessary neutralizing chemicals and clean-up materials. Ship’s personnel are not first responders and will act in a support role only, in the event of a spill. Drew Hamilton, Derek Coffman, and Theresa Miller have been trained in hazardous material response.

The Chief Scientist is directly responsible for the proper handling, both administrative and physical, of all scientific party hazardous wastes. No liquid wastes shall be introduced into the ship’s drainage system. No solid waste material shall be placed in the ship’s garbage.

10.0 RADIOACTIVE ISOTOPE POLICY

1. The BROWN has no specially designated lab space for working with isotopes. We will therefore require that all radioisotope work be done in a dedicated van with its own storage area and separate waste discharge. The policy is consistent with that of the UNOLS fleet. All of the waste should remain segregated from the ship's waste and be packed out by the investigator;

2. Each scientist working with these materials will be required to wear a lab coat and disposable booties to reduce the likelihood of tracking the substance out of the van into the ship;

3. It will be the responsibility of the investigator to conduct pre-cruise (for background) and post-cruise wipe tests (regardless of whether a spill occurred or not). Wipe tests should also be conducted in the event of a spill, as well as periodically while underway.

4. A detailed procedural methodology describing the use of these materials should be provided to the ship for review at least one month prior to bringing them aboard. A spill contingency plan should also be provided at that time. Please note that ship's personnel will not be a cleanup resource in the event of a spill;

5. A log detailing the type and amount of materials brought aboard and taken off the ship should be maintained, along with a record of any spills that occurred;

6. All radioisotope work will be conducted by NRC or State licensed investigators only, and copies of these licenses shall be provided to the ship at least one month prior to bringing any materials onboard.
 
 

11.0 MISCELLANEOUS

11.1 Radio interference

Radio transmission can interfere with several of the continuous data streams. If this becomes a problem, the Commanding Officer and Chief Scientist will work out a transmission schedule to minimize data interferences to the extent that vessel communication needs allow.

11.2 Pre & post-cruise meetings

A pre-cruise meeting between the Commanding Officer and the Chief Scientist will be conducted either the day before or the day of departure, with the express purpose of identifying day-to-day project requirements, in order to best use shipboard resources and identify overtime needs.

A post-cruise debriefing will be held between the Chief Scientist and the Commanding Officer.

11.3 Scientific berthing

The Chief Scientist is responsible for assigning berthing for the scientific party within the spaces approved as dedicated scientific berthing. The ship will send stateroom diagrams to the Chief Scientist showing authorized berthing spaces. The Chief Scientist is responsible for returning the scientific berthing spaces back over to the ship in the condition in which they were received; for stripping bedding and for linen return; and for the return of any room keys which were issued.

The Chief Scientist is also responsible for the cleanliness of the laboratory spaces and storage areas used by the science party, both during the cruise and at its conclusion prior to departing the ship.

In accordance with NC Instruction 5255.0, Controlled Substances Aboard NOAA Vessels, dated 06 August 1985, all persons boarding NOAA vessels give implied consent to conform with all safety and security policies and regulations which are administered by the Commanding Officer. All spaces and equipment on the vessel are subject to inspection or search at any time.

11.4 Emergency contacts

Prior to departure, the Chief Scientist must provide a listing of emergency contacts to the Executive Officer for all members of the scientific party, with the following information: name, address, relationship to member, and telephone number. These can be combined with the NOAA Health Services Questionnaire on the forms provided.

11.5 Weather deck Safety

Wearing open-toed footwear (such as sandals) on the weather decks is unsafe and is not permitted. This shipboard safety regulation is included in the Commanding Officer’s Standing Orders, and will be enforced. All members of the scientific party are expected to be aware of this regulation and to comply with it.

11.6 Wage marine dayworker working hours and rest periods

Chief Scientists shall be cognizant of the reduced capability of the RONALD H BROWN’s operating crew to support 24-hour mission activities with a high tempo of deck operations at all hours. Wage marine employees are subject to negotiated work rules contained in the applicable collective bargaining agreement. Dayworkers’ hours of duty are a continuous eight-hour period, beginning no earlier than 0600 and ending no later than 1800. It is not permissible to separate such an employee’s workday into several short work periods with interspersed nonwork periods. Dayworkers called out to work between the hours of 0000 and 0600 are entitled to a rest period of one hour for each such hour worked. Such rest periods begin at 0800 and will result in no dayworkers being available to support science operations until the rest period has been observed. All wage marine employees are supervised and assigned work only by the Commanding Officer or designee. The Chief Scientist and the Commanding Officer shall consult regularly to ensure that the shipboard resources available to support the embarked mission are utilized safely, efficiently and with due economy.

12.0 APPENDICES

(A) Cruise track

(B) List of chemicals onboard

(C) Van locations

13.0 APPROVAL OF INSTRUCTIONS

Approval of the final instructions shall be acknowledged in writing:
 
 

___________________________________________________

Rear Admiral John C. Albright, NOAA (date)

Director, Atlantic and Pacific Marine Centers
 
 

___________________________________________________

Dr. Eddie N. Bernard, NOAA (data)

Director, Pacific Marine Environmental Laboratory
 
 

Appendix A. Cruise Track
 
 


Cruise Track


Appendix B. List of chemicals
 
  Quantity Group Chemical

Location

On Ship

 
 
Compressed Gases  
carbon dioxide 2 tanks PMEL Aero van
helium 1 tank MISU NH3 van
helium 8 tanks PMEL AL van
breathing air 3 tanks PMEL AL van
balloon helium 60 tanks PMEL fantail
propane 1 tank PU Aero van
CO standard in nitrogen (5ppm) 1 tank UMD AOML van
oxygen 6 tanks AOML AOML van
zero-air 10 tanks AOML AOML van
NO in nitrogen (10 ppm) 1 tank AOML AOML van
nitrogen 1 tank UM 03 deck
nitrogen 1 tank MISU NH3 van
nitrogen 2 tanks CO2-AOML Hydro lab
standard air tanks 8 tanks CO2-AOML Hydro lab
CO  4 tanks IUP AOML van
NO in nitrogen (600 ppm) 2 tanks IUP AOML van
nitrogen 9 tanks IUP AOML van
zero-air 21 tanks IUP AOML van
liquid nitrogen 2 180 L SIO main lab
liquid nitrogen 6 180L tanks MPI  main lab
CO standard in air (5 ppm) 1 tank UMD AOML van
SO2 standard in air (5 0ppm) 1 tank UMD AOML van
NO standard in nitrogen (8 ppmv) 1 tank MPI MPI van
NO2 standard in nitrogen (10 ppmv)  1 tank MPI MPI van
CO standard in nitrogen (200 ppmv)  1 tank MPI MPI van
Synthetic air 2 tanks MPI MPI van
CO 2 tanks MPI MPI van
CH4 2 tanks MPI MPI van
N2O 2 tanks MPI MPI van
NO2 1 tank MPI MPI van
CO2 2 tanks MPI MPI van
Chemicals      
acetone 8 l  PMEL Main Lab
acetone 4 l CO2-AOML Hydro Lab
acetone 2.5 l MISU NH3 van
acetone 5 l SIO SIO van
acetonitrile 1 l MPI MPI van
2-aminoethanol 1l MISU NH3 van
ammonium chloride 500 g PMEL AL van
ammonium sulfate 1 kg PMEL AL van
borax 1 kg MISU NH3 van
butanol 32 l PMEL Ship’s HML
carbon 14 25 mci SIO SIO van
cadmium 250 g PMEL AL van
calcium sulfate (drierite) 10 kg PMEL AL van
charcoal 500 g PMEL AL van
charcoal  500g IUP AOML van
chromotropic acid 25g MPI MPI van
citric acid 2 kg PMEL AL van
Coulometer solution  8 l CO2-AOML Hydro Lab
cupric sulfate 500 g PMEL AL van
dimethylsulfide 25 ml PMEL AL van
dinitrophenylhydrazine 50g MPI MPI van
drierite 800 g MISU NH3 van
EDTA 300 g MISU NH3 van
ethanol 10 l MISU NH3 van
ethanol 6 l SIO SIO van
ethylenediamine tetraacetic acid (EDTA) 25 g PMEL AL van
ferric sulfate 500 g IUP AOML van
formaldehyde 37% 2 l MISU NH3 van
formaldehyde 37% 1 l MPI MPI van
glycerin 2 g on filters UMD AOML van
glycerol (30%) 1 l SIO SIO van
hexane 1 l PMEL AL van
hydrochloric acid 5 l PMEL AL van
hydrochloric acid 2 l SIO SIO van
hydrochloric acid (37%) 1 l MPI MPI van
hydrochloric acid (50%) 1 l PU Main Lab
hydrogen peroxide (33%) 4 l PMEL AL van
hydrogen peroxide (50%) 0.1 l MPI MPI van
hydrogen peroxide (30%) 1 l MPI MPI van
isopropyl alcohol 4 l PMEL AL van
isopropyl alcohol 500 ml PU Aero van
isopropyl alcohol 2 l CO2-AOML Hydro Lab
isopropyl alcohol 1 l IUP AOML van
luminol 100 g IUP AOML van
magnesium perchlorate 1 kg CO2-AOML Hydro Lab
methanesulfonic acid 500 ml PMEL AL van
methanol 7 l PMEL AL van
methanol 10 l SIO SIO van
methanol 500 ml PU Aero van
methanol 60 l MISU Ship’s HML
N-1-naphthyl-ethylenediamine dihydrochloride  80 g PMEL AL van
nitric acid 500 ml PU Aero van
OPA 2 g MISU NH3 van
OPA 200 g PMEL Main lab
Oxalic acid 6.3% in water 2 x 100ml MPI MPI van
Palladium on alumina 500 g UMD AOML van
paraformaldehyde (30%) 1 l MPI MPI van
PEA (phenyl ethanol amine) 60 ml SIO SIO van
pH buffer solutions 1 l MISU NH3 van
pH buffer solutions 1.5 l PMEL Main lab
phosphoric acid 1 l PMEL AL van
platinum-aluminum oxide pellets 25 g IUP AOML van
potassium carbonate 2 kg PMEL AL van
potassium carbonate 2 g on filters UMD AOML van
potassium hydroxide 100 g IUP AOML van
potassium iodide 500 g CO2-AOML Hydro Lab
potassium iodate 25 g PMEL AL van
potassium permanganate 6.3% in water 3 x 50ml MPI MPI van
scintillation cocktaim 12 l SIO SIO van
silica gel 2 kg MPI MPI van
sodium acetate 2 kg MISU NH3 van
sodium bisulfite 39% in water 1 l MPI MPI van
sodium citrate 2 kg PMEL Main lab
sodium hydroxide 2 kg PMEL AL van
sodium hydroxide 50% 2 l MISU NH3 van
sodium hydrogen phosphate 1 kg MISU NH3 van
sodium sulfite 1 kg MISU NH3 van
sodium sulfite 200g PMEL Main lab
sodium sulfite 100g IUP AOML van
sulfanilamide solution 80 l PMEL AL van
sulfuric acid 5 l PMEL AL van
sulfuric acid 2 l MPI MPI van
Titantetrachloride 34% in HCl (37%) 2x 0.5l MPI MPI van
       

 

C. Van locations